How long have you had the vehicle and do you know how long it has been a dual fuel vehicle? It is an aftermarket LPG conversion, correct?
LPG will not get as many kms as petrol will. It just doesn't burn as well, and power is reduced.
You may want to check what the timing advance is, as most of these installations require the installer to physically advance the timing. The LPG computer will retard the timing by adjusting the signal to the coil.
I know it's a little confusing, but if the system is working properly then the timing should be the same as factory for petrol, and advanced for LPG. If someone messed up your timing it can mess with the programming of the LPG computer.
It is also possible that the injectors from both LPG and petrol are operating at the same time, or one of the LPG solenoids is leaking while on petrol. Or, your fuel pump is not shutting down while on LPG and it is causing the injectors to leak.
Sorry, I know it's a lot of stuff that probably doesn't help. Can you be more specific on exactly what has been done, and what type of engine it is?