All that sludgy stuff at the radiator cap is probably radiator stop leak stuff. They were probably trying to slow the leak down a little. Apparently, it didn't work very well.
I'd double check what's coming out of your A/C drain - it's probably condensate - water. But it's faintly possible that the heater core could be leaking and (not sure how the HVAC is arranged inside) it could end up draining there. So if it's coolant - heater core.
You might also try cleaning the area around that leak on the head really well, and then driving it briefly, and looking again. Sometimes coolant can trickle along edges and crevices for a distance from the source, and make it look like something is leaking that isn't.
HG failures can have all sorts of different symptoms, depending on where it's leaking. There's compression, oil, crankcase interior, and coolant all right next to each other. What gets mixed with what it shouldn't get mixed with is random.