sounds like you found a great 4Runner and have been given a bunch of great advice.
On top of what others have stated. I think the best bang for your buck in terms of driveability and handling (especially when towing) is to swap out your oem rubber sway bar bushings to polyurethane. Measure the bars twice and order once from jegs or summit racing. both have greasable and non-greasable versions available in all sizes.
I would also replace the PCV. It's an inexpensive OEM part that is often overlooked yet performs a pretty important function for the engine crankcase pressure regulation.
Drop in a good fuel system cleaner (techron) with your next full tank of gas.
Get a new engine air filter (if needed)
Get a new cabin air filter (behind glovebox, just yank it out and check it) if needed.
verify the towing electrical connection works (before taking delivery or driving it off the lot) sinc eyou'll be towing right away.. harbor freight sells a plug in tester for cheap, buy it, use it, return it. Free check.
I'd do an engine oil change (and filter) with Mobil 1.
I'd use Mobil 1 75W-90 for the differentials and transfer case
(mobil 1 is available at walmart so a great value)
lube the driveshaft zerks (I use mobil1 but everyone has their opinion)
only use Toyota SLCC (replace the hoses, clamps and thermostat while you have it all apart.. no point skimping) and timing belt parts.
wiper blades are important, windshield washer fluid is just as important (especially having a spare bottle in the Runner during winter months in the midwest/ north... don't want to get stranded on a highway with none). Carry an extra bottle (the kind that won't freeze)
Make sure your tires are properly inflated
Lastly, get some good tunes, food, and navigation (I use Waze app and lot it) for the road trip.
Drive safe and let us know when you arrive in the PNW.. Post some pics of your journey as well.. you're gonna drive through some great parts of the country.