The belt is every 100k miles, not sure if the chain ever needs to replaced. I'm sure it does eventually but I don't think it has a set maintenance interval.
Timing chains do need to be replaced. Usually after 250k miles. The nice thing about a chain it usually lets you know when it's starting to go. Chains usually don't break..but they do stretch and this can cause it to slip a gear. And the V6 is an interference engine..this could mean an end to the engine.
I usually keep my vehicles well past 300k miles...so I may be looking at a timing chain replacement. I haven't replaced a timing chain on a vehicle in over 30 years. Timing belts are far less complicated...so not sure if I'll do the job or just take it to a mechanic or just buy a new truck when the chain starts to make noise. So far it's fine...just under 200k miles.