100 Octane
'Only' $5.69???? Wow!
That is probably aviation gasoline, so be careful. AVGAS contains lead, which is illegal to use in your 4Runner and could harm the engine.
I doubt you would see any enhanced performance, so save your money. Fill it up with pump gas rated at '93' and pour in a bottle of Octane Boost and you'll get the same result. 100 octane is overkill and unnecessary for your truck.
Cam 2 fuel and other racing gasoline is best for older engines with very high compression ratios (such as 12.0:1, etc.).
My friend had a customized 1969 427-powered Chevelle that needed it, but it was pushing 620+ horsepower and he drag-raced it. It would not run on unleaded "pump" gas, unless he poured additives into the tank beforehand.
My 4Runner ran just fine on 87 octane, so I do not see how the huge extra cost of super-high octane gasoline could be justified for this type of vehicle.