The location rear passenger has not proven a good location for a Group 31. Group 31 is 75+ lbs. That location is not re-enforced, it will cause damage to the vehicle if you actually wheel it. The only re-enforced locations I am aware of are the stock battery location and the location exact opposite of it on the passenger side.
It is possible I run JUST a group 31 (100 ah). I am investigating the dual battery options at this time. If I do dual battery I am keeping Group 31 as Aux.
What I am saying is put the group 31 in the stock location (making sure you have a bracket that can fit the 31 and the ML-ACR (my bracket for the stock position will not, but I believe Off Grid's new ones will, ask before you order). Then you put a 35 or other smaller battery in the passenger location.
Wire everything to the 31 in the stock location. Wire up a switch to the ML-ACR so you can force link the batteries from the cabin by pressing a button (my thread covers this).
Now, if the main battery (the 31) cannot start the car because you partied too hard, or left the fridge open the night before, you can press the button and crank the engine. If the battery is truly dead where it cannot supply enough current to move the ML-ACR solenoid (there is a 7 amp peak burst to move the magnetic latch), then you pop the hood and manually latch the solenoid. Now, crank the engine.
The only place I see this getting you in trouble is if the main battery somehow acts as a dead load and prevents the backup battery from cranking the engine, or it slowly drains the backup and then overloads the alternator. In this unlikely scenario you'd have to disconnect the main battery and manually latch the solenoid.
Also, are you going to run a winch? If so, I have some suggestions with regard to cabling - I'm in the process of designing my winch install now.
*edit*
Whoops, I missed the part where you said you have a compressor on the passenger fender. I'm planning to put a compressor on the other side, behind the fuse box, with the Slee bracket. If I need a tank, I'll put it in the drivers side wheel well, though that looks like a process I'd like to avoid.
Do you need to relocate the secondary air injection pump to use the passenger forward area? If so, where are you going to put that?