TDC exhaust would be with the timing mark at 180 though, right?
No. Think about the strokes of the engine. The crank will make one full revolution for the intake stroke and another full revolution for the exhaust stroke. If the head is off of the engine, then the exhaust and intake stroke is irrelevant.
When re-installing the head, put the #1 piston to TDC and the pulley timing mark should be at 0* TDC. Install the head as normal then put the cam gear on the end of the cam with the little dot at the 1130 position with the timing chain on the gear. You should be good from there.
I would read over the whole process in the FSM first so you're familiar with the process. Don't be like me and miss a step that will cause you to completely tear down your engine. It will make you feel like a dumb ass.