I'll defer to someone more technical to answer that.
Here is my experience ... I've owned my 1997 4Runner since 67K around mid 2002. I'm now at 232K miles and it's been 13 years.
My first CV joint BOOT went out in mid 2012 with over 200k miles on the ODO.
My other CV joint BOOT started to leak due to cracks a few weekends ago in Moab.
When you look at a CV you can see that just with normal movement they get plenty of stretch so I don't understand what you mean by taking it apart and stretching it. The most likely thing to happen if you take off a 10 year old CV boot is it will fall apart and then you will be replacing it early.
When a CV boot leaks it isn't the end of the world. It doesn't even mean you have to stop your trip. Just drive it home at the end of the trip then replace the boot and fully clean and re-grease the insides of the CV. It is the kind of thing you fix within a week or two. Just make sure you don't go 6 months and let crud or salt get up in there.
The only real preventative maintenance would be to find a spare CV and bring it with you on trips (I don't do this but perhaps I should consider it) AND to check the boots for cracks and tears every few months.
If you want your CV boots to last another 200,000 miles then replace them with OEM Toyota boots.