Since you have never done this before, you may want to talk to the machine shop and ask them what would be best.
That being said if you do it yourself it's not that hard to do, but if I were removing the valves for what ever reason, I would "lap" the valves, what this is, lapping a valve is using a valve lapping tool (this can be a hand tool or and electric tool) and valve lapping compound, what is involved is after each valve is removed, I usually remove them all and use a piece of card board with small holes in it to keep the valves in order so the go back into the same location, be sure to label in the card board so you know which way is which, etc., etc., so now you have the valves out, apply some lapping compound and the sealing face/edge of a valve, insert it back into it's location, using the lapping tool you want to rotate the valve against the valve seat repeatedly in the head with pressure, what you're doing here is "re-seating" the valve to the valve seat, you don't want to go overboard when doing this, what you want to achieve is a even dull finish (usually when you remove a valve it and the seat contact/seating areas will be shiny) on both the valve seat and the valve where it contacts the seat, once you get both the valve and the seat looking the same dull finish you know the valve and seat will seal properly.
Here's a link to some valve lapping tools, to use the "plunger" looking hand lapping tools, you stick the rubber plunger end to the flat surface of the valve and then applying pressure toward the head and rotating the tool back and forth rapidly between your palms like you're trying to start a fire with a stick, do this for a few minutes and then remove the valve, clean the valve and seat and inspect to see if you have the dull finish on the seating areas uniformly.
To use an electric tool, it much the same but the tool does the rotation and you just have to apply pressure, but it goes much faster so do it a few seconds at a time until you get the hang of it.
If you have a valve that will not get a complete uniform dull gray lap, that's a bad valve, i.e. usually a warped valve.
valve lapping tool, - Search
Go to YouTube and check some videos on lapping valves.
Also if you can find an old small gas engine to practice on, it will help build your confidence and doing some of these things.