Waste of Money
Something is combustible, such as gasoline, because it is in the right proportions as a fuel and has an oxidizer present to ignite from a spark, which is like a car running on gasoline. Gasoline obviously combusts in the proportions of 87-93 (ratings) and probably even higher and lower than that but I would dare say you see little improvement in performance or gas mileage to make up for the cost of paying 0.10 - 0.20 more per gallon. Some folks will scream up and down that their car runs better and they get better gas mileage, but lots of folks are cured from illnesses by placebos (sugar pills) all the time. I think most of it is in their head!
Don't waste your money on higher Octane fuel for a daily driver! Maybe in your race car...
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Brian