flux capacitor
The energy in these caps is too small to make it safe for all usage scenarios.
One problem is that some cars have electronics that uses a constant energy for alarm system, radio door locks etc.
This capacitor pack holds some 10Wh energy at 12V but you can't actually recover it all as the voltage wont stay high enough. A lead battery typically comes with 16 Wh per Pound or in the case of this video, 320Wh or so. That's 30+ times less reserve for use of radio/light when engine is off.
Do you think this will work? long term? The only thing I am having trouble understanding is electronics.
The capacitor charges and discharges extremely fast; batteries don't. You also risk damaging your electrical circuits through-out your vehicle. That is not worth gambling the integrity of your electrical system. Especially since it's a whole lot of ass pain to troubleshoot electrical gremlins. It's a big risk for such a small reward.
We have a saying in the electrical world: "If it ain't broke, don't fix it."