Perhaps I misunderstand the connection the transfer case has to the transmission.
When the transmission is placed in neutral, or park for that matter, energy is transferred to the transmission via the fluid in the TQ and the internals of the transmission will start spinning. This is just a no load, fluid coupling with the internals of the trans simply spinning because they are connected.
To keep this simple, lets forget about 4wd. The transfer case is basically a pass through for the transmission to get power to the rear axle. When you place the transfer case into neutral, the part of the transfer case that is connected to the output shaft of the transmission will start to spin as well. There is fluid in the transfer case, so given enough time, everything else may start spinning.