If thats what you want there is a single wire that runs to the AC compressor. That is what actually engages the AC. I think you would be better off tapping off of the relay inside or even the switch so that the fans don't cycle when the defrost is on. are you just not sure which wire on the relay to tap into?
Like i said on the AC compressor itself is the trigger wire for the AC clutch. It will be a positive 12v signal though. You would need to run this through a relay anyway, so you can change the polarity if your fans are set to run off of a negative trigger.