The e-lockers are little stubborn at times. I was riding in a friends rig this weekend that has Toyota e-lockers front and rear (it's a solid axle fully built Toyota pickup that is an amazing trail rig). Anyway, he has his e-locker manually wired up and they would still stick momentarily from time to time. Overall they work pretty well, but the engagement is not always instant like an air locker.
There also seems to be a bit of a break in period with all lockers. My air locker have always engaged instantly, but they were a bit stubborn about disengagement at first. Now they seem to be pretty much instant both on and on off.