The serpentine belt is the same as the accessory belt, which the v6 has and needs to be checked. Yes, you're right that the v6 has a timing chain (this is a different thing entirely).
If you look on the Problems and Warranty Issues sections of this forum, you may find other things that need to be checked (i.e. various TSBs, sunroof rattle, frozen caliper, etc).
Good luck!