Same thing happened to me with my 2006 Toyota 4Runner about two weeks ago. I was driving to work about 6:30AM and had the defrost on including the one for the rear window. The temperature was in the low 50's. About 20 minutes into my drive, I noticed a burnt smell, but didn't think anything of it because I assumed it was coming from the outside air. At the same time, I noticed that my rear window had cleared up so I turned off the defrost. Moments later, the entire back window exploded. For a second, I thought someone had shot my back window out. After I parked my car, I went to the back of the car to see if I could find anything that is not broken glass. I didn't see anything (bullet, rock, etc.). I had my window replaced the very same day and the window installer pointed out to me that the metal strip for the defrost was burnt. Not only that, one of the (2) wire connectors for the defrost was fried. I called the Toyota Dealership that I had purchased the car from and they said that the car was out of warranty (3 yrs/36.000 mi) and have not heard of such an incident. I have not filed a report with Toyota yet, but intend to do so in the next few days.