Guys, use this calculator
Combined gas law calculator - Chemistry Online Education to determine what your pressure would be at a certain temperature.
The combined gas law (Boyle, Charles, Lussac) is a combination of laws that go through a lot of complicated derivations to get:
(P1V1)/T1=(P2V2)/T2.
P1 is your initial pressure
V1 is your initial volume
T1 is your initial air temp
P2 is your pressure after you heat it up with your engine
V2 is your final volume (should be the same as V1)
T2 is whatever your temp is at max engine heat
Solve for P2, or work it backwards and solve for P1. I did it and used 100 degrees F to start and 250 degrees F as max temp. I used a volume of 144 inches cubed and the pressure rise was like 32 psi or something. Make sure you convert the units to what you understand though lol.
I would worry about a valve malfunction before I would worry about engine heat raising pressure to a dangerous level.
Edit: I did not work this formula out by hand to make sure the calculator was correct but there is no reason why it wouldn't. It's a simple formula.
Google combined gas law for interesting reading.