Well, hold on now. It may be something simple like something in the cabin filter like previously suggested. Let's cross our fingers. Now, I went to the repair manual and wow, you do NOT want to try and take this task on. Basically have to remove the whole dash, seats etc.
I also found two web sites that give some hints on Mold remediation in vehicle AC units. One site said mold CANT grow on the evaporator, because it is in a sealed unit. (Which seems to be the case when I viewed the illustrations in the repair unit). But, due to condensation in the vent system, mold can grow. The other site suggested mold growing on the condenser, (which is not in a sealed box) can and often does get into the air intake for a vehicles HVAC system, causing a smell.
So the solution from both sources is getting mold killing stuff into the vent system. (And on the condenser). There are a few ways of doing this.
Tonight, after you take out the cabin filter and check it for dead things, keep it out a couple of minutes. Get a can of Lysol, turn on the vhicle, turn the fan on high, Spray the can of Lysol until your finger hurts. Watch you face, don't want to blow that stuff in your eyes. While you are spraying, change the "Mode" button so the spray goes through all the vents. Feet, body and defrost.
Next, place the filter back in, or a new filter, then find the air intake from the outside of the vehicle. I think it is that grill work right under the windshield wipers, but I cant be sure about that. I could not find anything in the engine compartment which looks like air intake for the cabin, but looking at the repair manual, the whole HVAC/blower etc unit is right under those vents behind the dash.
Again, with the fan on, spray the Lysol through the grill work, (assuming I am right and that grill work is the intake.) One way to determine if I am right, turn on the fan and listen at the grill work, should hear the air going through.....in any case, that should kill the mold for now, freshen the car and your wife will love you again. Be safe.